FUW TRENDS IN SCIENCE & TECHNOLOGY JOURNAL

(A Peer Review Journal)
e–ISSN: 2408–5162; p–ISSN: 2048–5170

FUW TRENDS IN SCIENCE & TECHNOLOGY JOURNAL

CHARACTERIZATIONS OF TIO2 THIN FILMS PREPARED FROM METAL-ORGANIC LIQUID PRECURSOR AT DIFFERENT DEPOSITION TEMPERATURE
Pages: 43-46
Ogunmola Enoch D., Adeoye Abiodun E., Ajenifuja Emmanuel, Taleatu Bidini A, Omotoso Ezekiel


keywords: Titanium dioxide, thin films, MOCVD, coatings, micrograph, optical properties

Abstract

Thin films of TiO2 were prepared on glass substrates at varied deposition temperature using metal-organic liquid precursor by simple chemical vapor deposition technique. The deposition process was carried out at 350, 380, 420 and 480oC for samples TiOT1, TiOT2, TiOT3 and TiOT4, respectively. Characterizations of the films were carried out using UV-Vis-NIR spectrophotometry, field emission scanning electron microscopy (FE-SEM), energy dispersive x-ray spectroscopy and Sign at one four-point probe coupled with Keithley source meter 2400. The uv-visible optical studies revealed that the films transmitted between 65 and 85% mainly in the visible region. Hence, depending on deposition temperatures, energy band gap values between 1.53 and 3.26 eV were obtained. Refractive indices were also estimated between 2.55 and 3.50. Estimating from the sectional FE-SEM analysis, slight differences in the film thickness was observed. Film thickness in the range of 131.11–132.01 nm was determined. Sheet resistivity of the films ranged between 596.32 to 7694.79 Ωm

References

Adeoye AE, Ajenifuja E, Taleatu BA, & Fasasi YA 2015. Rutherford Backscattering Spectrometry Analysis and Structural Properties of Zn𝑥b1−𝑥 Thin Films Deposited by Chemical Spray Pyrolysis. Journal of Materials, 2015, 8. Ajayi OB1970. Electrical and Optical Properties of Pyrolytically Deposited Indium Oxide. (M.Sc.Thesis). Ajenifuja E, Fasasi AY & Osinkolu GA 2012. Sputtering-Pressure Dependent Optical and Microstructural Properties Variations in DC Reactive Magnetron Sputtered Titanium Nitride Thin Films. Transactions of the Indian Ceramic Society, 71(4): 181-188. Ajenifuja E, Osinkolu GA, Fasasi AY, Pelemo DA & Obiajunwa EI 2016. Rutherford backscattering spectroscopy and structural analysis of DC reactive magnetron sputtered titanium nitride thin films on glass substrates. J Mater Sci: Mater Electron, 27: 335. Babelon P, Dequiedt AS, Mostesa-Sba H, Bourgeois S, Sibillot P & Sacilotti M 1998. Thin Solid Films, 322: 63. Banakh O, Schmid PE, Sanjines R & Levy F 2002. Electrical and optical properties of TiOx thin films deposited by reactive magnetron sputtering. Surf. Coat. Techn., 151-152, 272-275. Castaneda L, Alonso JC, Ortiz A, Andrade E, Saniger JM & Banuelos JG 2002. Spray pyrolysis deposition and characterization of titanium dioxide thin films. Material Chemical Physiccs, 77: 938. Deite SK 2006. Semiconductor Material and Device Characterization. (3. Edition, Ed.) Durusoy HZ, Duyar O, Aydinli A & Ay A 2003. Influence of substrate temperature and bias voltage on the optical transmittance of TIN Films. Vacuum, 70: 21-28. Enzo S, Fagherazzi G, Benedetti A & Polizzi S 1989. A profile-fitting procedure for analysis of broadened X-ray diffraction peaks. I. Methodology. J. Appl. Cryst., 22: 184. Ida T& Toraya H 2002. Deconvolution of the instrumental functions in powder X-ray diffractometry. J. Appl. Cryst., 35, 58. Jin-Cherng H, Paul WW & Cheng-Chung L 2006. X-ray photoelectron spectroscopy study of thin TiO2 films cosputtered with Al. Applied Optics, 45(18): 4303-4309. Kiran MS, Ghanashyam KD & Padmanabhan KA2008. Appl. Surf Sci., 255: 1934-1941. Maissel LI & Glang R 1970. Hand book of thin film Technology. New York, USA: MC Graw Hill co. Matsui V, Yamamoto Y & Takeda S 2000. Stability in electrical properties of ultra thin tin oxide films. Mat. Res. Symp. Proc., 621: 4.9.1-4.9.6. Niyomsoan S, Grant W, Olson DL & Mishra B 2002. Variation of color in titanium and zirconium nitride decorative thin films. Thin Solid Films, 415, 187-194. Ogunmola ED, Famojuro AT, Olofinjana B, Akinwunmi O, Ojo IA & Ajayi EOB 2015. Synthesis and Properties of Titanium Nitride Thin Films Prepared by Metal Organic Chemical Vapour Deposition Technique. Int. J. Materials Chem. & Phy., 1(3), 308-322. Pal U, Saha S, Chaudhury AK, Rao VV & Banerjee HD 1989. Some optical properties of evaporated zinc telluride films. J. Phys., D(22): 965. Savaloni H, Khojier K & Alaee MS2003. characteristics of nanostructure and electrical properties of Ti thin films as a function of substrate temperature and film thickness. J. Mater. Sci., 42, 2603. Savaloni H, Taherizadeh A & Zendehnam A 2004. Residual stress and structural characteristics in Ti and Cu sputtered films on glass substrates at different substrate temperatures and film thickness. Physica B, 349: 44. Tang H, Berger H, Schmid PE, Levy F, Gritsyna VT & Shirley DA 1993. Photoluminescence in TiO 2 anatase single crystals. Solid state Commun., 87: 847. Vanessa GV, Yudith OL, Jesús SG, Alejandro LO& Virginia HC-M 2014. TiO2 Films Synthesis over Polypropylene by Sol-Gel Assisted with Hydrothermal Treatment for the Photocatalytic Propane Degradation. Scientific Res., Green & Sustainable Chem., 4: 120-132. Vorotilov KA, Orlova EV & Petrovsky VI 1992. Sol-gel TiO2 films on silicon substrates. Thin Solid Films, 207: 180.

Highlights